A few things to consider.
For fastest charging and best battery life, you want the charging algorithm to be fairly intelligent. This is why people switched over their Charger/Converters from the models in the 1990's to mid-late 2000's to the ones with "smart Wizard charging".
Alternators in general will not be putting out more than maybe half their rated power at engine idle. Your best charging will be while driving down the highway at a decent constant speed.
Having a larger alternator does mean it could handle pushing more amps to the coach for charging. But, does not mean it will push more amps to the coach. This is because the coach and engine batteries are hooked together with the alternator, and most alternator's have a simplistic charging algorithm - something like around 14.4V until it decides the battery is full enough to switch over to 14.2V or maybe 13.8V (that seems to be what my alternator does). The coach deep cycle batteries if lead acid want about 14.8V when low, then maybe 14.4, then less when at 90% or something and go into float mode.
1) Using a single engine alternator limits you to the charging the starter battery needs, so 14.4V at most. This will not give you a fast charge with a lot of amps to your coach batteries. Voltage determines how forcefully electricity is 'pushed' to the batteries. Then the state of the batteries determines how many amps the battery is willing to receive at that voltage.
2) I never really looked into them because my engine is already crowded enough, but I believe dual alternators can be configured so one alternator charges the engine and the other charges the coach. Then if you've bought a high-end alternator with built-in intelligent charging controller, it can give lots of amps to the coach (provided the engine revs are decent, not at idle).
3) Adding a Battery-to-Battery charger, like Sterling B2B chargers for boats and RVs, will allow for good and fast charging of the coach. They work by putting the B2B in-line between the alternator and coach batteries (I put mine after my isolator). Then the B2B takes whatever the incoming voltage is from the alternator, 14.4V or 14.2V or 13.8V, and increases the voltage according to its smart programmable charge algorithm and reading of the state of the coach batteries, and sends that to the coach. Because the coach sees, say, 14.8V it will charge properly and at high amps. This is not a free lunch, the increased voltage comes at decreasing the amps coming in from the alternator (e.g. the alternator is seeing 40 amps being output, but the coach batteries are getting 30A coming in, with the lost amps going to upping the voltage, and losses in the B2B during the conversion process itself).
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Alternator amps Battery-2-Battery Coach example amps
14.4V 5A not using one 14.4V 5A
14.4V 40A 14.4->14.8 14.8V 30A or so
I added a Sterling B2B charger years ago and went from barely charging the coach while driving to charging at a much better rate than my (upgraded Wizard) charger/converter. That was with stock 130A alternator (from 1998). I recently upgraded to a 200A alternator, mostly because my engine was open getting its spark plugs, etc, replaced and the labor to swap in a new alternator at the same time was almost nothing, so bigger and newer just seemed like a good idea.
Note if you do install a B2B, it is one-way only. So even though my isolator might be 2-way, after putting the B2B along the path to the coach batteries, I can no longer jump start the engine from coach. I meant to rig a switch to allow bypassing the B2B so I could jump start if needed, but have so far not done it.
4) If you don't have the usual Lead Acid coach batteries, which basically matches your engine battery type, then using just a normal alternator with cheap lead acid charging algorithm isn't a good idea. Do NOT use straight alternator charging if you switch to Lithium!