Not to be too emphatic, but I would say 100% absolutely NOT. Did I mention "not" "ever"?
I'll explain how I got there. My background is in boating. There are dozens of pieces of hardware on boats that are sealed with bedding (which is a way to say caulked, although sometimes other compounds are used). Ports (windows) are one of them. Boats pound through seas, often taking "green water" (i.e. solid water) over the deck - not just spray. They also flex while doing so. There is not much harder on a seal than that.
Hardware (including ports/windows) that is bedded always has some sort of flange or "faying surface." Basically a flat area that mates to the surface of the boat (these days, commonly gelcoat, just like our Chinooks). The bedding (caulk) goes UNDER this flange. Anything that oozes out is trimmed or wiped neatly away, as it serves no purpose in sealing, and can actually start to trap dirt/water, plus looks horrible.
Anything that is bedded, eventually needs to be re-bedded. It may be five, ten, twenty, or fifty years later (boats last a looooong time), but it will happen. If it's not done prophylactically, then it's usually at the first sign of a leak. The part is pulled, the surfaces are cleaned and prepped, the sealant (bedding compound or caulk) is put between the two surfaces (underneath the window or hardware flange), the items are put together, any squeeze out is cleaned up, the joint is tested, and then you go on your merry way for another decade or whatever, ploughing your way through the sea, pounding, flexing, etc. The ports/hardware don't leak until it's time to bed again (way in future).
However, there are always people who, through lack of knowledge, bad advice, or laziness, decide not to pull the hardware, but instead to run a bead of caulk AROUND the outside of the joint. This can indeed fix the leak....sometimes even for a week or two

Then they usually show up at the boatyard. Either right away with the continuing leaks; or five years later with rot and damage that make the job ten times more expensive.
Caulk around the outside is like if you have a bandaid on a wound and it starts to fall off, so you put another band-aid around the edge instead of taking the first one off and replacing it. A real "band-aid" fix.
I have noticed that this "rim around the outside" is quite common in the RV world. To me it's totally nonsensical. Either the bedding under the flange/fasteners is working or it isn't. If it is, there is no need for anything on the outside of the joint or on top of the fasteners. That just collects dirt and looks bad. If it isn't, then it's time to pull the item, clean and prep, re-bed, and go on your way for another decade. With a clean, tidy rig that doesn't have blobs of dirty caulk on the outside of everything.
Can you tell this is a pet peeve of mine?
I guess I could have just said "No, I don't."
PS: I have put something like a bead of butyl tape, or even "masking" tape (but an outdoor type) over a leak if it was discovered on a trip. But that's just to get me home to where I can fix it for real.
PPS: So if your windows are leaking, I would pull them, clean/prep, then re-seal them. I'd use a good quality butyl tape, such as "Bed-It" --- but you could also use some other high-quality sealant.